Xianhe Zhao

Ph.D., lecturer

E-Mail：

zhaoxh@lzu.edu.cn

2017-Prensent     College of chemistry and Chemical Engineering, Lanzhou University, 

                            State Key Laboratory of Applied Organic Chemistry, Lecturer

2010-2017           Lanzhou University (Advisor: Chun-An FAN), D.Sc

2006-2010           Liaocheng University, B.Sc

· Research Topics

Natural Product Synthesis and Synthetic Methodology

· Publications

1. Asymmetric Divergent Synthesis of Ent-Kaurane-, Ent-Atisane-, Ent-Beyerane-, Ent-Trachylobane-, and Ent-Gibberellane-Type Diterpenoids. Xian-He Zhao, Le-Le Meng, Xiao-Tao Liu, Peng-Fei Shu, Cheng Yuan, Xian-Tao An, Tian-Xi Jia, Qi-Qiong Yang, Xiang Zhen, and Chun-An Fan*, J. Am. Chem. Soc., 2023, 145, 311.

2. Palladium-Catalyzed Asymmetric (4 + 2) Annulation of gamma-Methylidene-delta-valerolactones with Alkenes: Enantioselective Synthesis of Functionalized Chiral Cyclohexyl Spirooxindoles. Zhi-Long Jia, Xian-Tao An, Yu-Hua Deng, Lin-Han Pang, Chun-Fang Liu, Le-Le Meng, Jia-Kun Xue, Xian-He Zhao*, and Chun-An Fan*, Org. Lett. 2021, 23, 745-750.

3. Tandem (2 + 2) Annulation/Retro-4 pi Electrocyclization/Imino-Nazarov Cyclization Reaction of p-Quinone Methides with Ynamides: Expeditious Construction of Functionalized Aminoindenes. Ke-Yin Yu, Yu-Hua Deng, Xiao-Min Ge, Xian-Tao An, Peng-Fei Shu, Ye-Xing Cao, Xian-He Zhao*, and Chun-An Fan*, Org. Lett. 2021, 23, 5885-5890.

4. Asymmetric Catalytic [4+5] Annulation of Ortho-Quinone Methides with Vinylethylene Carbonates and Its Extension to Stereoselective Tandem Rearrangement. Xiantao An, Jiyuan Du, Zhilong Jia, Qing Zhang, Keyin Yu, Yizhou Zhang, Xianhe Zhao, Ran Fang, and Chunan Fan*. Chem.-Eur. J.  2020, 26, 3803-3809.

5. Palladium-Catalyzed Asymmetric (2+3) Annulation of p-Quinone Methides with Trimethylenemethanes: Enantioselective Synthesis of Functionalized Chiral Spirocyclopentyl p-Dienones. Zhilong Jia, Xiantao An,Yuhua Deng,Huibin Wang, Kangji Gan, Jing Zhang, Xianhe Zhao*, and Chunan Fan*.  Org. Lett. 2020, 22, 4171-4175.

6. Total Synthesis of (±)-Lycojaponicumin D and Lycodoline-Type Lycopodium Alkaloids. Xianhe Zhao, Qing Zhang, Jiyuan Du, Xinyun Lu, Yexing Cao, Yuhua Deng, and Chun-An Fan*. J. Am. Chem. Soc. 2017, 139, 7095-7103.

7. Asymmetric Total Synthesis of Apocynaceae Hydrocarbazole Alkaloids (+)-Deethylibophyllidine and (+)-Limaspermidine. Du Jiyuan, Zeng Chao, Han Xiaojie, Qu Hu, Zhao Xianhe, An Xiantao, and Fan Chunan*. J. Am. Chem. Soc. 2015, 137, 4267-4273.

8. Bioinspired Total Synthesis of Montanine-Type Amaryllidaceae Alkaloids. Bao Xu, Cao Yexing, Chu Wendao, Qu Hu, Du Jiyuan, Zhao Xianhe, Ma Xiaoyan, Wang Chengtao, and Fan Chunan*.  Angew. Chem. Int. Ed. 2013, 52, 14167-14172.

9. Asymmetric Catalytic 1,6-Conjugate Addition/Aromatization of para-Quinone Methides: Enantioselective Introduction of Functionalized Diarylmethine Stereogenic Centers. Chu Wendao, Zhang Lefen, Bao Xu, Zhao Xianhe, Zeng Chao, Du Jiyua, Zhang Guobiao, Wang Fangxin, Ma Xiaoyan, and Fan Chunan*.  Angew. Chem. Int. Ed. 2013, 52, 9229-9233.