•Education and Experience
2009 - Present College of chemistry and Chemical Engineering, Lanzhou University,
State Key Laboratory of Applied Organic Chemistry, Professor
2007-2009 The University of Chicago, USA (Advisor: Chuan He), Postdoc
2006-2007 Peking University, China (Advisor: Zhangjie Shi), Postdoc
2003-2006 Lanzhou University, China (Advisor: Yongmin Liang), Ph.D.
1993-1997 Lanzhou University, China , B.Sc.
•Honors and Rewards
2015 Thieme Chemistry Journal Award
2013 The Most Cited of Hundred Papers Award in China
2013 The second prize in China's State Natual Science Award (number four)
2011 Program for New Century Excellent Talents in University
•Resaerch Topics
1.Transition-metal catalyzed C-P bond formation
2.Transition-metal catalyzed C-C and C-H bond activation
•Publications
1. Palladium-Catalyzed Relay C-H Functionalization to Construct Novel Hybrid-Arylcyclophosphorus Ligand Precursors. Juan Wang, Peng-Bo Bai, and Shang-Dong Yang*, Chin. Chem. Lett. 2022, 33, 2397.
2. Lewis Acid-Catalyzed Pudovik Reaction-Phospha-Brook Rearrangement Sequence to Access Phosphoric Esters. Jin Yang, Dang-Wei Qian, and Shang-Dong Yang*, Beilstein J. Org. Chem. 2022, 18, 1188.
3. Temporary (PQO) directing group enabled carbazole ortho arylation via palladium catalysis, Zhi-Chao Qi, Qin-Xin Lou, Yuan Niu and Shang-Dong Yang*, Chem. Commun. 2021, 57, 2021-2024
4. Visible-light-facilitated P-center radical addition to CQX (X = C, N) bonds results in cyclizations. Chong Li, Juan Wang and Shangdong Yang*, Chem. Commun. 2021, 57, 7997-8002.
5. Heck Reaction Boosted Heterocycle Ring-Closing and Ring-Opening Rearrangement: A Strategy for the Synthesis of Indolyl-Type Ligands. Chong Li, Zhi-Chao Qi, Jing-Yu Li and Shangdong Yang*, J. Org. Chem. 2021, 86, 16977-16991.
6. The sequential C–H oxidation/asymmetric phosphonylation of primary alcohols to synthesize α-hydroxy phosphonates, Shifu Ying, Xiaoling Huang, Xinwei Guo and Shang-Dong Yang*, Green Synth. and Catal. 2021, 2, 315-319.
7. Enantioselective Cobalt-Catalyzed Reductive Cross-Coupling for theSynthesis of Axially Chiral Phosphine-Olefin Ligands, Xi Zhang, Juan Wang and Shang-Dong Yang*, ACS Catal. 2021, 11, 14008-14015.
8. New Staudinger Strategy Enabled N-Acyl Phosphinamidites Synthesis, Yuan-Yuan Zhu, Gang-Wei Wang, Jin Yang and Shang-Dong Yang*, CCS Chem., 2021, 3, 1702-1709.
9. Concise synthesis of N-phosphorylated amides through three-component reactions, Yuan-Yuan Zhu, Tao Zhang, Linlin Zhou and Shangdong Yang*, Green Chem. 2021, 23, 9417-9421.
10. Recent advances in the synthesis and applications of phosphoramides, Y Yuan-Yuan Zhu, Yuan Niu, Yan-Ning Niu and Shangdong Yang*, Org. Biomol. Chem. 2021, 19, 10296-10313.
11. Iridium(III)-Catalyzed C-H Functionalization of Triarylphosphine Oxides with Diazo Dicarbonyl Compounds: Synthesis of α-Aryl 1,3-Dicarbonyl Derivatives, Qin-Xin Lou, Jing-Yu Li and Shangdong Yang*, Synlett, 2021, 32, 1365-1370.
12. Recent advances in radical phosphorylation, Yuan Niu and Shangdong Yang*, Chem. Synth. 2021, 1, 12-14.
13. Ir(III)-Catalyzed C−H Functionalization of Triphenylphosphine Oxide toward 3‑Aryl Oxindoles. Qinxin Lou, Yuan Niu, Zhichao Qi, and Shangdong Yang*. J. Org. Chem. 2020, 85, 14527-14536.
14. Copper-catalyzed arylation of polycyclic aromatic hydrocarbons by the P=O group. Yuan Niu, Zhichao Qi, Qinxin Lou, Pengbo Bai, and Shangdong Yang*. Chem. Commun. 2020, 56, 14721-14724.
15. Diastereoselective Synthesis of P-Chirogenic and Atropisomeric 2,2'-Bisphosphino-1,1'-binaphthyls Enabled by Internal Phosphine Oxide Directing Groups. Chong Li, and Shangdong Yang*. Chinese J. Org. Chem. 2020, 40, 2159-2160.
16. Bismuth(III)-Catalyzed Sequential Enamine-Imine Tautomerism/2-Aza-Cope Rearrangement of Stable β-Enaminophosphonates: One-Pot Synthesis of β-Aminophosphonates. Ming Jin, Shifu Yin, Shangdong Yang*. Org. Lett. 2020, 22, 2811-2815.
17.Generation of a Key Synthon of Indole Alkaloid Synthesis by Palladium(II)-Catalyzed Indole 2-Methylenephosphorylation. Yuan Niu, Pengbo Bai, Qinxin Lou, and Shangdong Yang*. ChemCatChem 2020, 12, 3644-3649.
18. Allylation of β-amino phosphonic acid precursor via palladium-NHC catalyzed allylic C-H activation. Wei Ren, Ming Jin, QianmingZuo, and Shangdong Yang*. Org. Chem. Front. 2020, 7, 298-302.
19. Photo-induced phosphorus radical involved semipinacol rearrangement reaction: Highly synthesis of γ-oxo-phosphonates. Chunhai Wang, Xiaoling Huang, Xueting Liu, Suqian Gao, Bin Zhao, and Shangdong Yang*. Chinese Chem. Lett. 2020, 31, 677-680.
20. Pd-Catalyzed Heck-Type Reaction: Synthesizing Highly Diastereoselective and Multiple Aryl-Substituted P‑Ligands. Chong Li, Xiaoyue Qiang, Zhichao Qi, Bin Cao, Jingyu Li, and Shangdong Yang*. Org. Lett. 2019, 21, 7138-7142.
21. Visible photocatalysis of novel oxime phosphonates: synthesis of β-aminophosphonates. Yonghong Li, Chunhai Wang, Suqian Gao, Fengming Qi, and Shangdong Yang*. Chem. Commun. 2019, 55, 11888-11891.
22. Palladium-NHC-Catalyzed Allylic Alkylation of Pronucleophiles with Alkynes. Wei Ren, Qianming Zuo, Yanning Niu, and Shangdong Yang*. Org. Lett. 2019, 21, 7956-7960.
23. Applications of transition metal catalyzed P-radical for synthesis of organophosphorus compounds. Wei Ren, Qiang Yang, and Shangdong Yang*. Pure Appl. Chem. 2019, 91, 87-94.
24. NHCs-Catalyzed the Synthesis of Benzazole-Phoshpine Ligands under Air Condition. Wei Ren, Qianming Zuo, and Shangdong Yang*. Synlett 2019, 30, 1719-1724.
25. Visible-light-induced tandem phosphorylation cyclization of vinyl azides under mild conditions. Yonghong Li, Yuanyuan Zhu , and Shangdong Yang*. Org. Chem. Front. 2018, 5, 822-826.
26. Rh(III)-Catalyzed Phosphine Oxide Migration Reactions: Selective Synthesis of 3-Phosphinoylindoles. Chunhai Wang, and Shangdong Yang*. Chem-Asian J. 2018, 13, 2401-2404.
27. Autoxidation Photoredox Catalysis for the Synthesis of 2‑Phosphinoylindoles. Chunhai Wang, Yonghong Li, and Shangdong Yang*. Org. Lett. 2018, 20, 2382-2385.
28. Visible-Light-Catalyzed Phosphonation-Annulation: An Efficient Strategyto Synthesize β-Phosphonopyrrolidines and β-Phosphonolactones. Chong Li, Zhichao Qi, Qiang Yang, Xiaoyue Qiang, and Shangdong Yang*. Chinese J. Chem. 2018, 36, 1052-1058.
29. Direct Allylic C(sp3)‑H Alkylation with 2‑Naphthols via Cooperative Palladium and Copper Catalysis: Construction of Cyclohexadienones with Quaternary Carbon Centers. Ming Jin, Wei Ren, Dangwei Qian, and Shangdong Yang*. Org. Lett. 2018, 20, 7015-7019.
30. Photocatalyzed Intermolecular Aminodifluoromethylphosphonation of Alkenes: Facile Synthesis of a,a-Difluoro-g-aminophosphonates. Qiang Yang, Chong Li, Zhichao Qi, Xiaoyue Qiang, and Shangdong Yang*, Chem.-Eur. J. 2018, 24, 14363-14367.
31. New Approaches for Biaryl-Based Phosphine Ligand Synthesis via P=O Directed C−H Functionalizations. Yanna Ma, Shixia Li, and Shangdong Yang*. Acc. Chem. Res. 2017, 50, 1480-1492.
32. Highly Efficient and Divergent Construction of Chiral γ‑Phosphono-α-Amino Acids via Palladium-Catalyzed Alkylation of Unactivated C(sp3)−H Bonds. Qiang Yang, and Shangdong Yang*. ACS Catal. 2017, 7, 5220-5224.
33. Direct Allylic C−H Bond Activation To Synthesize [Pd(η3‑cin)(IPr)Cl] Complex: Application in the Allylation of Oxindoles. Rongbin Hu, Chunhai Wang, Wei Ren, Zhong Liu, and Shangdong Yang*. ACS Catal. 2017, 7, 7400-7404.
34. Diastereoselective Radical Oxidative C−H Aminations toward Chiral Atropoisomeric (P,N) Ligand Precursors. Yanna Ma, Mingxing Cheng, and Shangdong Yang*. Org. Lett. 2017, 19, 600-603.
35. Palladium-Catalyzed Migratory Insertion of Isocyanides for Synthesis of C‑Phosphonoketenimines. Qiang Yang, Chong Li, Mingxing Cheng, and Shangdong Yang*. ACS Catal. 2016, 6, 4715-4719.
36. Enantioselective synthesis of arylglycine derivatives by direct C–H oxidative cross-coupling. Xiaohong Wei, Gangwei Wang, and Shangdong Yang*. Chem. Commun. 2015, 51, 832-835.
37. A unique Copper-catalyzed Cross-coupling Reaction by Hydrogen (H2) Removal for the Stereoselective Synthesis of 3-phosphoindoles. Anxi Zhou, Liuliang Mao, Gangwei Wang, and Shangdong Yang*. Chem. Commun. 2014, 50, 8529-8532.
38. Regio- and Stereoselective Allylic C−H Arylation with Electron-Deficient Arenes by 1, 1′-Bi-2-naphthol−Palladium Cooperation. Gangwei Wang, Anxi Zhou, Shixia Li, and Shangdong Yang*. Org. Lett. 2014, 16, 3118-3121.
39. Direct Annulations toward Phosphorylated Oxindoles by Silver-Catalyzed Carbon-phosphorus Functionalization of Alkenes. Yamin Li, Meng Sun, Hongli Wang, Qiuping Tian, and Shangdong Yang*. Angew. Chem. Int. Ed. 2013, 52, 3972-3976.
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