应功能有机分子化学国家重点实验室邀请,英国爱丁堡大学Uwe Schneider 博士来我校进行交流并做学术报告,欢迎感兴趣的师生参加。
报 告 人:Uwe Schneider 博士
报告题目:Catalyst Design & Serendipity in Organic Synthesis
报告时间:2019年7月8日(星期一)上午 10:00
报告地点:第一化学楼1001学术报告厅
报告人简介
Uwe Schneider was born in Würzburg, Germany, and studied Chemistry in Germany as well as in France. He received a Ph.D. degree in Organic Chemistry at IRCOF, France, with Professor Pannecoucke and Professor Quirion (2003). Next, he did his ERATO postdoctoral work with Professor Shu Kobayashi at the University of Tokyo, before being appointed as an Assistant Professor at the University of Tokyo (2007). Subsequently, he moved to the University of Edinburgh, UK, to become a Lecturer (2011). His research interests include the development of both new catalysts and new reactions.
报告摘要
The seminar summarizes the development of new low-oxidation state catalysts in synthesis: (i) a potentially ambiphilic Ga(I) species formed in situ from gallium metal; (ii) a basic C(0) species, i.e., a carbodiphosphorane. In addition, the functionalization of challenging C–H bonds by non-precious metal–base catalysts will be detailed: (i) the sodium amide-triggered allylic C(sp3)–H bond activation of aromatic alkenes; (ii) the copper(I)/lithium carbonate-catalyzed C2-selective Mannich-type reactions with various N-unprotected indoles.
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