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李 灿

李 灿
李 灿
中国科学院院士
邮箱:
canli@dicp.ac.cn
通讯地址:
辽宁省大连市沙河口区中山路457号中国科学院大连化学物理研究所
·教育背景、工作经历

2011-至今                        大连洁净能源国家实验室(筹),主任

2007.02-2007.03              澳大利亚昆士兰大学,客座教授

2007-2012                       大连化学物理研究所,副所长

2007.01-2007.12              大连化物所与英国BP公司联合能源创新实验室,主任

2003.03-2003.04              法国巴黎六大,特邀教授

2000.01-2000.03              美国里海大学,客座教授

2000.11-2000.12              日本东京大学、早稻田大学、北海道大学、东京理工学院、日本筑波材料科学研究所,访问教授

2000-至今                        中国-法国催化联合实验室,主任

1999.01-1999.03              英国利物浦大学,客座教授

1998-至今                        大连化物所催化基础国家重点实验室,主任

1994-1996                       美国西北大学,博士后,客座教授

1993.9-至今                     大连化物所,研究员

1990-1993.08                  大连化物所,副研究员

1990.10-1990.12              比利时天主教鲁汶大学,访问学者

1989-1990                       大连化学物理研究所,助理研究员

1986-1988                       大连化学物理研究所-东京工业大学联合培养博士,理学博士

1983-1985                       大连化学物理研究所,物理化学 硕士

1978-1980/1981-1983      河西学院/陕西师范大学 学士

·荣誉奖励

2019                                亚太催化成就奖

2018                                中国光谱成就奖

2017                                日本光化学奖

2014                                全国杰出科技人才奖

2014                                中国催化成就奖

2011                                国家自然科学二等奖

2008                                当选欧洲人文和自然科学院外籍院士

2005                                中国科学院杰出成就奖

2005                                当选发展中国家科学院院士

2005                                何梁何利奖

2005                                英国皇家化学会Fellow

2004                                国际催化奖

2003                                当选中国科学院院士

2003                                国家归国杰出科学家奖

2001                                日本科学促进会客座教授

1999                                国家技术发明二等奖

1999                                国家优秀科学家奖

1998                                中国杰出青年科学家奖

1997                                香港求是“杰出青年学者奖”

1996                                国家基金委杰出青年科学基金资助

1994                                中国杰出青年科学家奖

1993                                中国科学院杰出青年科学家奖

1993                                中国科学院自然科学奖

·研究兴趣

从事催化材料、催化反应和催化光谱表征方面的研究,包括绿色催化研究,环境催化研究,多相手性催化研究,DNA催化研究以及原位光谱表征研究等。2001年来,主要致力于太阳能科学转化的研究,包括光催化、光电催化分解水制氢及二氧化碳还原和新型太阳电池的基础研究。

·代表成果

A UV Raman Spectroscopic Identification of active sites in Zeolites and Zeolite Synthesis

A-1. UV resonance Raman spectroscopic identification of titanium atoms in the framework of TS-1 zeolite, Can Li*, Guang Xiong, Qin Xin, Jianke Liu, Pinliang Ying, Zhaochi Feng, Jian Li, Wubin Yang, Yongzhong Yang, Guiru Wang, Xiyao Liu, Min Lin, Xieqing Wang and Enze Min, Angewandte Chemie International Edition, 1999, 38, 2220-2222.

A-2. Characterization of iron atoms in the framework MFI-type zeolites by UV resonance Raman spectroscopy, Yi Yu, Guang Xiong, Can Li and Fengshou Xiao*, Journal of Catalysis, 2000, 194, 487-490.

A-3. Identifying the isolated transition metal ions/oxides in molecular sieves and on oxide supports by UV resonance Raman spectroscopy, Can Li*, Journal of Catalysis, 2003, 216, 203-212. (Invited paper for 40th Commemorative Issue)

A-4. Framework Fe ions in Fe-ZSM-5 zeolite studied by UV resonance Raman spectroscopy and density functional theory calculations, Keju Sun, Fengtao Fan, Haian Xia, Zhaochi Feng, Weixue Li and Can Li*, Journal of Physical Chemistry C, 2008, 112, 16036-16041.

A-5. In situ UV Raman spectroscopic study on the synthesis mechanism of AlPO-5, Fengtao Fan, Zhaochi Feng, Keju Sun, Meiling Guo, Qiang Guo, Yu Song, Weixue Li and Can Li*, Angewandte Chemie International Edition, 2009, 48, 8743-8747.

A-6. UV Raman spectroscopic studies on active sites and synthesis mechanisms of transition metal-containing microporous and mesoporous materials, Fengtao Fan, Zhaochi Feng and Can Li*, Accounts of Chemical Research, 2010, 43, 378-387.

A-7. UV Raman spectroscopic study on the synthesis mechanism and assembly of molecular sieves, Fengtao Fan, Zhaochi Feng and Can Li*. Chemical Society Reviews, 2010, 39, 4794-4801.

A-8. A Thorough Investigation on the Active Titanium Species in TS-1 Zeolite by In Situ UV Resonance Raman Spectroscopy, Qiang Guo, Keju Sun, Zhaochi Feng, Guanna Li, Meiling Guo, Fengtao Fan*, and Can Li*, Chemistry-A European Journal, 2012, 18, 13854-13860.

B UV Raman Spectroscopic Characterization of Photocatalysts (phase junction)

B-1. Phase transformation in the surface region of zirconia detected by UV Raman spectroscopy, Meijun Li, Zhaochi Feng, Guang Xiong, Pinliang Ying, Qin Xin, Can Li*, Journal of Physical Chemistry B, 2001, 105, 8107-8111.

B-2 UV Raman spectroscopic study on TiO2. I. Phase transformation at the surface and in the bulk, Jing Zhang, Meijun Li, Zhaochi Feng, Jun Chen and Can Li*, Journal of Physical Chemistry B, 2006, 110, 927-935.

B-3 Surface phases of TiO2 nanoparticles studied by UV Raman spectroscopy and FT-IR spectroscopy, Weiguang Su, Jing Zhang, Zhaochi Feng, Tao Chen, Pinliang Ying and Can Li*, Journal of Physical Chemistry C, 2008, 112, 7710-7716.

B-4 Importance of the relationship between surface phases and photocatalytic activity of TiO2, Jing Zhang, Qian Xu, Zhaochi Feng, Meijun Li and Can Li*, Angewandte Chemie International Edition, 2008, 47, 1766-1769.

B-5 Enhancement of photocatalytic water oxidation activity on IrOx-ZnO/Zn2-xGeO4-x-3yN2y catalyst with the solid solution phase junction, Baojun Ma, Jinhui Yang, Hongxian Han, Jiantao Wang, Xiaohong Zhang and Can Li*, Journal of Physical Chemistry C, 2010, 114, 12818-12822.

B-6 Photocatalytic Overall Water Splitting Promoted with α-β Phase Junction on Ga2O3, Xiang Wang, Qian Xu, Mingrun Li, Shuai Shen, Xiuli Wang, Yaochuan Wang, Zhaochi Feng, Jingying Shi, Hongxian Han and Can Li*, Angewandte Chemie International Edition, 2012, 51, 13089-13092.

C Catalytic Reactions in Nanoreactors

C-1 Enantioselective epoxidation of olefins catalyzed by Mn(salen)/MCM-41 synthesized with a new anchoring method, Song Xiang, Yiliang Zhang, Qin Xin and Can Li*, Chemical Communications, 2002, 2696-2697.

C-2 Asymmetric epoxidation of allyl alcohol on organic-inorganic hybrid chiral catalysts grafted onto the surface of silica and in the mesopores of MCM-41, Song Xiang, Yiliang Zhang, Qin Xin and Can Li*, Angewandte Chemie International Edition, 2002, 41, 821-824.

C-3 Chiral synthesis on catalysts immobilized in microporous and mesoporous materials, Can Li*, Cataysis Reviews, 2004, 46, 419-492.

C-4 Chiral catalysis in nanopores of mesoporous materials, Can Li*, Huidong Zhang, Dongmei Jiang and Qihua Yang, Chemical Communications, 2007, 547-558.

C-5 Enhanced cooperative activation effect in the hydrolytic kinetic resolution of epoxides on [Co(salen)] catalysts confined in nanocages, Hengquan Yang, Lei Zhang, Lin Zhong, Qihua Yang* and Can Li*, Angewandte Chemie International Edition, 2007, 46, 6861-6865.

C-6 Mesoporous organic-inorganic hybrid materials built using polyhedral oligomeric silsesquioxane blocks, Lei Zhang, Hendrikus C. L. Abbenhuis, Qihua Yang*, Yimeng Wang, Pieter C. M. M. Magusin, Brahim Mezari, Rutger A. van Santen* and Can Li*, Angewandte Chemie International Edition, 2007, 46, 5003-5006.

C-7 Asymmetric ring-opening of epoxides on chiral Co(Salen) catalyst synthesized in SBA-16 through the “ship in a bottle” strategy, Hengquan Yang, Lei Zhang, Weiguang Su, Qihua Yang* and Can Li*, Journal of Catalysis, 2007, 248, 204-212.

C-8 Enhancement of the performance of a platinum nanocatalyst confined within carbon nanotubes for asymmetric hydrogenation, Zhijian Chen, Zaihong Guan, Mingrun Li, Qihua Yang and Can Li*, Angewandte Chemie International Edition, 2011, 50, 4913-4917.

C-9 Oxygen evolution from water oxidation on molecular catalysts confined in the nanocages of mesoporous silicas, Bo Li, Fei Li, Shiyang Bai, Zhijun Wang, Licheng Sun, Qihua Yang* and Can Li*, Energy & Environmental Science, 2012, 5, 8229-8233.

C-10 Hydration of Epoxides on [CoIII(salen)] Encapsulated in Silica-Based Nanoreactors, Bo Li, Shiyang Bai, Xuefeng Wang, Mingmei Zhong, Qihua Yang*, Can Li*, Angewandte Chemie International Edition, 2012, 51, 11517-11521.

D Co-catalysts in Photocatalysis

D-1 Enhancement of photocatalytic H2 evolution on CdS by loading MoS2 as cocatalyst under visible light irradiation, Xu Zong, Hongjian Yan, Guopeng Wu, Guijun Ma, Fuyu Wen, Lu Wang, and Can Li*, Journal of the American Chemical Society, 2008, 130, 7176-7177.

D-2 Visible-light-driven hydrogen production with extremely high quantum efficiency on Pt-PdS/CdS photocatalyst, Hongjian Yan, Jinhui Yang, Guijun Ma, Guopeng Wu, Xu Zong, Zhibin Lei, Jingying Shi and Can Li*, Journal of Catalysis, 2009, 266, 165-168.

D-3 The synergistic effects of two co-catalysts on Zn2GeO4 on photocatalytic water splitting, Baojun Ma, Fuyu Wen, Hongfu Jiang, Jinhui Yang, Pinliang Ying and Can Li*, Catalysis Letters, 2010, 134, 78–86.

D-4 Photocatalytic water oxidation on BiVO4 with the electrocatalyst as an oxidation cocatalyst: Essential relations between electrocatalyst and photocatalyst, Donge Wang, Rengui Li, Jian Zhu, Jingying Shi, Jingfeng Han, Xu Zong, and Can Li*, Journal of Physical Chemistry C, 2012, 116, 5082-5089.

D-5 Roles of Cocatalysts in Photocatalysis and Photoelectrocatalysis, Jinhui Yang, Donge Wang, Hongxian Han, and Can Li*, Accounts of Chemical Research, 2013, 46, 1900-1909.

D-6 Spatial Separation of Photogenerated Electrons and Holes among {010} and {110} Crystal Facets of BiVO4, Rengui Li, Fuxiang Zhang, Donge Wang, Jingxiu Yang, Mingrun Li, Jian Zhu, Xin Zhou, Hongxian Han and Can Li*, Nature Communications, 2013, 4, 1432.

D-7 Dual Cocatalysts Loaded Type I CdS/ZnS Core/Shell Nanocrystals as Effective and Stable Photocatalysts for H2 Evolution, Lei Huang, Xiuli Wang, Jinhui Yang, Gang Liu, Jingfeng Han, and Can Li*, The Journal of Physical Chemistry C, 2013, 117 , 11584-11591.

E Ultra Deep Desulfurization

E-1 Ultra-deep desulfurization of diesel: Oxidation with a recoverable catalyst assembled in emulsion, Can Li*, Zongxuan Jiang, Jinbo Gao, Yongxing Yang, Shaojun Wang, Fuping Tian, Fuxia Sun, Xiuping Sun, Pinliang Ying, Chongren Han, Chemistry-A European Journal, 2004, 10, 2277-2280.

E-2 Ultra-deep desulfurization of diesel by selective oxidation with [C18H37N(CH3)3]4[H2NaPW10O36] catalyst assembled in emulsion droplets, Hongying Lü, Jinbo Gao, Zongxuan Jiang, Fei Jing, Yongxing Yang, Gang Wang and Can Li*, Journal of Catalysis, 2006, 239, 369-375.

E-3 Hydrodesulfurization of 4,6-DMDBT on a multi-metallic sulfide catalyst with layered structure, Lu Wang, Yongna Zhang, Yuliang Zhang, Peng Liu, Hongxian Han, Min Yang, Zongxuan Jiang* and Can Li*, Applied Catalysis A: General, 2011, 394, 18-24. 

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