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曾会应

2021-01-04 09:29:00
曾会应
曾会应
博士、教授、博士生导师
邮箱:
zenghy@lzu.edu.cn
· EDUCATION AND EXPERIMENCE

2021-至 今           兰州大学化学化工学院、功能有机分子化学国家重点实验室,教授

2016-2020           兰州大学化学化工学院、功能有机分子化学国家重点实验室,副教授

2013-2015           加拿大McGill University(麦吉尔大学),(合作导师: Prof. Chao-Jun Li),博士后

2005-2010           南开大学,(导师: 李卫东教授),博士

1999-2003           湖南师范大学,学士

• 荣誉奖

       2023                     隆基教学骨干奖

2021                    “甘肃省领军人才”第二层次人选

2021                     Thieme Chemistry Journals Award

2020                     教育部“长江学者奖励计划”青年学者

2020                     甘肃省普通高等学校青年教师成才奖

2020                     兰州大学“萃英学者”

2020                     兰州大学“优秀学生思想政治工作者”

2019                     兰州大学”课程思政”示范课程讲课比赛一等奖

2013                     加拿大优秀博士后奖学金

• 研究兴趣

绿色化学,木质素降解、光促进无金属无光敏剂的绿色合成、有机合成反应

• 代表成果

1. Recent Advances in Photo-Induced Organic Synthesis in Water. Qian Dou, and Huiying Zeng*, Curr. Opin. Green Sustain. Chem.2023, 40, 100766.

2. Iodomethane as an Organocatalyst for the Aerobic Ortho-Selective Trifluoromethylation of Pyridines. Jianjin Yu, Renqin Zhan, Chao-Jun Li, Huiying Zeng*, Sci. Chin. Chem. 2023, 66,133.

3. Visible-Light-Induced Transition-Metal and Photosensitizer Free Decarbonylative Addition of Amino-Arylaldehydes to Ketones. Yi Wang, Yatao Lang, Chao-Jun Li, and Huiying Zeng*, Chem. Sci. 2022, 13, 698.

4. Visible-Light-Induced Cross-Coupling of Aryl Iodides with Hydrazones via EDA-Complex. Pan Pan, Shihan Liu, Yu Lan*, Huiying Zeng*, and Chao-Jun Li*, Chem. Sci. 2022, 13, 7165.

5. Cleavage/Cross-Coupling Strategy for Converting beta-O-4 Linkage Lignin Model Compounds into High Valued Benzyl Amines via Dual C-O Bond Cleavage. Le Jia, Chao-Jun Li, and Huiying Zeng*, Chin. Chem. Lett. 2022, 33, 1519.

6. Visible-Light Induced Transition-Metal and Photosensitizer-Free Conversion of Aldehydes to Acyl Fluorides under Mild Conditions. Yatao Lang, Xinlong Han, Xiangjun Peng, Zhong Zheng, Chao-Jun Li, and Huiying Zeng*, Green Synth. Catal. 2022, 3, 373.

7. Base-Promoted Catalyst-Free Regioselective Hydroacylation of Styrenes with Hydrazones via Carbanion Addition. Pan Pan, Yatao Lang, Dawei Cao, Huiying Zeng*, and Chao-Jun Li*, CCS Chem. 2022, 4, 3254.

8. Cleavage/Cross-Coupling Strategy for Converting beta-O-4 Linkage Lignin Model Compounds into High Valued Benzyl Amines via Dual C-O Bond Cleavage.  Le Jia, Chao-Jun Li, and Huiying Zeng*, Chinese Chemical Letters202233, 1519.

9. Dearomatization-Rearomatization Strategy for ortho‐Selective Alkylation of Phenols with Primary Alcohols. Jianjin Yu, Chaojun Li*, and Huiying Zeng*.  Angew. Chem. Int. Ed. 2021, 60, 4043–4048.

10. Photo-Induced Transition-Metal and External Photosensitizer-Free Organic Reactions. Yatao Lang, Chao-Jun Li, and Huiying Zeng*, Org. Chem. Front. 20218, 3594-3613.

11. Dearomatization–Rearomatization Strategy for Palladium-Catalyzed C–N Cross-Coupling Reactions. Yatao Lang, Chao-Jun Li*, and  Huiying Zeng*, Synlett 202132, 429-435. 

12. Photoinduced Transition-Metal and External Photosensitizer Free Phosphonation of Unactivated C(sp2)-F Bond via SET Process under Mild Conditions.  Qian Dou, Li Geng, Bin Cheng*, Chao-Jun Li*, and Huiying Zeng*, Fundamental Research 2021, 1, 742-746.

13. Light-Driven MPV-Type Reduction of Aryl Ketones/Aldehydes to Alcohols with Isopropanols under Mild Conditions. Dawei Cao, Shumei Xia, Pan Pan, Huiying Zeng*, Chao-Jun Li*, and Yong Peng*, Green Chem. 2021, 23, 7539-7543.

14. Coupling without Coupling Reactions: En Route to Developing Phenols as Sustainable Coupling Partners via Dearomatization/Rearomatization Processes. Zihang Qiu, Huiying Zeng* and Chaojun Li*. Acc. Chem. Res. 202053, 2395–2413.

15.  Photoinduced Catalyst-Free Deborylation-Deuteration of Arylboronic Acids with D2O. Yatao Lang, Xiangjun Peng, Chaojun Li, and Huiying Zeng*. Green Chem. 202022, 6323–6327. (Selected as “2020 HOT Green Chemistry Article” and “Inside Cover Paper”. News story describing this work was highlighted in CBG https://www.chembeango.com/zixun/50983)

16. Photoinduced Transition-Metal- and External-Photosensitizer-Free Intramolecular Aryl Rearrangement via C(Ar)-O Bond Cleavage. Qian Dou, Chaojun Li, and Huiying Zeng*. Chem. Sci. 202011, 5740–5744. (News story describing this work was highlighted in CBG https://www.chembeango.com/zixun/50427)

17. Dearomatization−Rearomatization Strategy for Synthesizing Carbazoles with 2,2-Biphenols and Ammonia by Dual C(Ar)−OH Bond Cleavages. Dawei Cao, Jing Yu, Huiying Zeng*, and Chaojun Li*. J. Agr. Food Chem. 202068, 13200-13205.

18. Palladium-Catalyzed Aerobic Synthesis of ortho-Substituted Phenols from Cyclohexanones and Primary Alcohols. Huiying Zeng*, Jianjin Yu, and Chaojun Li*. Chem. Commun. 202056, 1239–1242. (News story describing this work was highlighted in Organic Chemistry Portal. https://www.organic-chemistry.org/Highlights/2020/ 12October.shtm)

19. Two-in-One Strategy for Palladium-Catalyzed C–H Functionalization in Water. Huiying Zeng*, Zemin Wang, and Chaojun Li*. Angew. Chem. Int. Ed. 201958, 2859-2863.

20. Dearomatization-Rearomatization Strategy for Reductive Cross-Coupling of Indoles with Ketones in Water. Zemin Wang, Huiying Zeng*, and Chaojun Li*. Org. Lett. 201921, 2302–2306.

21. Construction of Spirocycle Tetrahydro-β-carbolines via Cross-Annulation of phenols with Tryptamines in Water. Zemin Wang, Jiabin Niu, Huiying Zeng*, and Chaojun Li*. Org. Lett. 201921, 7033–7037.

22. Umpolumg Cross-Coupling of Polyfluoroarenes with Hydrazones via Activation of C-F Bonds. Dawei Cao, Pan Pan, Huiying Zeng*. and Chaojun Li*. Chem. Commun. 201955, 9323–9326.

23. Metal-Free Construction of the C(sp3)-CF3 Bond: Trifluoromethylation of Hydrazones with Togni’s Reagent udner Mild Conditions. Huiying Zeng*, Zhen Luo, Xinlong Han, and Chaojun Li*. Org. Lett.201921, 5948–5951.

24. Photoinduced Transition-Metal-Free Cross-Coupling of Aryl Halides with H-Phosphonates. Huiying Zeng*, Qian Dou, and Chaojun Li*. Org. Lett. 201921, 1301-1305.

25. Hydrogen Bonding Promoted Simple and Clean Photo-Induced Reduction of C–X Bond with Isopropanol. Dawei Cao, Chaoxian Yan, Panpan Zhou, Huiying Zeng*, and Chaojun Li*. Chem. Common. 201955, 767-770.

26. Palladium-Catalyzed Formal Cross-Coupling of Diaryl Ethers with Amines: Slicing the 4-O-5 Linkage in Lignin Models. Huiying Zeng*, Dawei Cao, Zihang Qiu, Chaojun Li*. Angew. Chem. Int. Ed. 201857, 3752-3757.

27. Formal Cross-Coupling of Diaryl Ethers with Ammonia by Dual C(Ar)−O Bond Cleavages. Dawei Cao, Huiying Zeng*, and Chaojun Li*. ACS Catal. 20188, 8873-8878.

28. An Adventure in Sustainable Cross-Coupling of Phenols and Derivatives via Carbon−Oxygen Bond Cleavage. Huiying Zeng*, Zihang Qiu,  Alejandra Dominguez-Huerta, Zoe Hearne, Zhengwang Chen, and Chaojun Li*. ACS Catal. 20177, 510-519.

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