邵向锋
2009-至今 功能有机分子化学国家重点实验室、兰州大学化学化工学院，教授
2008-2009 日本大阪府立大学、日本京都大学，博士后
2005-2008 日本京都大学（导师： 矢持 秀起 教授），博士后
2004-2005 日本科学技术振兴机构（导师： 矢持 秀起 教授），博士后
2001-2004 中国科学院化学研究所 (导师: 朱道本 院士、张德清 研究员)，理学博士
1998-2001 兰州大学 (导师: 刘中立 教授)，理学硕士
1994-1998 兰州大学，理学学士
•荣誉奖励
2015 国家自然科学基金委“优秀青年科学基金”
•研究兴趣
有机功能分子设计合成、分子组装以及组装材料的“光-电-磁”性能研究
•代表成果
1. Monoazadichalcogenasumanenes: Synthesis, Structures, and Ring Reconstruction via Atom Transfer under Acidic Conditions. Jihai Shang, Renjie Wang, Chengshan Yuan, Zitong Liu, Hao-Li Zhang, and Xiangfeng Shao*, Angew. Chem. Int. Ed. 2022, 61, e202117504.
2. Bottom-Up Preparation of Twisted Graphene Nanoribbons via Cu-Catalyzed Deoxygenative Coupling. Yuan Gao, Xinqiang Hua, Wei Jiang, Chun-Lin Sun, Chengshan Yuan, Zitong Liu, Hao-Li Zhang, and Xiangfeng Shao*, Angew. Chem. Int. Ed. 2022, 61, e202210924.
3. A Tellura-Baeyer-Villiger Oxidation: One-step Transformation of Tellurophene into Chiral Tellurinate Lactone. Shitao Wang, Chaoxian Yan, Wenlong Zhao, Xiaolan Liu, Cheng-Shan Yuan, Hao-Li Zhang, and Xiangfeng Shao*. Chem. Sci. 2021, 12, 5811-5817.
4. Transforming Electron-Rich Hetero-Buckybowls into Electron-Deficient Polycycles. Zhe Liu, Wenru Song, Chaoxian Yan, Zitong Liu*, Hao-Li Zhang, and Xiangfeng Shao*. Org. Chem. Front. 2021, 8, 4767-4776.
5. Synthesis and Derivatization of Hetera-Buckybowls. Wenbo Wang, and Xiangfeng Shao*. Org. Biomol. Chem. 2021, 19, 101-122.
6. TTF-fused Hetera-Buckybowl: Protonation-Induced Electron Transfer and Self-Sensitized Photooxidation. Lei Liu, Chaoxian Yan, Yecheng Li, Zhe Liu, Chengshan Yuan*, Hao-Li Zhang, and Xiangfeng Shao*. Chem.-Eur. J. 2020, 26, 7083–7091.
7. Chemistry of Hetera-Buckybowl Trichalcogenasumanene. Dongxu Li, and Xiangfeng Shao*. Synlett 2020, 31, 1050–1063.
8. A Semipinacol Rearrangement of Vinylogous α-Ketol Cocatalyzed by Cinchona-Based Primary Amine and N-Boc-phenylglycines: Mechanisms, Roles of Catalysts and Origin of Enantioselectivity. Chaoxian Yan, Fangling Yang, Ka Lu, Xing Yang, Panpan Zhou*, and Xiangfeng Shao*.Org. Chem. Front. 2020, 7, 1845–1861.
9. Efficient Construction of Near-Infrared Absorption Donor-Acceptor Copolymers with and without Pt(II)-Incorporation toward Broadband Nonlinear Optical Materials. Jibin Sun*, Zitong Liu, Chaoxian Yan, Xingming Sun, Zheng Xie, Guanxin Zhang, Xiangfeng Shao*, Deqing Zhang*, and Shuyun Zhou. ACS Appl. Mater. Inter. 2020, 12, 2944–2951.
10. Doping Sumanene with both Chalcogen and Phosphorus(V): One-Step Synthesis, Coordination and Selective Response toward Ag(I). Shitao Wang, Chaoxian Yan, Jihai Shang, Wenbo Wang, Chengshan Yuan, Haoli Zhang, and Xiangfeng Shao*. Angew. Chem. Int. Ed. 2019, 58, 3819–3823.
11. A“Phase Separation” Molecular Design Strategy Towards Large-Area 2D Molecular Crystals. Beibei Fu, Cong Wang, Yantao Sun, Jiarong Yao, Yu Wang, Fayuan Ge, Fangxu Yang, Zheyuan Liu, Yanfeng Dang, Xiaotao Zhang, Xiangfeng Shao, Rongjin Li*, and Wenping Hu. Adv. Mater. 2019, 31, 1901437.
12. Why Electrostatically Enhanced Thiourea Is Better Than Schreiner’s Thiourea in Both Catalytic Activity and Regioselectivity? Chaoxian Yan, Ruizhi Wu, Ka Lu, Fangling Yang, Xiaoshan Yang, Rui Wang, Xing Yang, Panpan Zhou*, and Xiangfeng Shao*. Org. Chem. Front. 2019, 6, 1821-1831.
13. Trichalcogenasumanenes Containing various Chalcogen Atoms: Synthesis, Structure, Property, and Chemical Reactivity. Shitao Wang, Jihai Shang, Chaoxian Yan, Wenbo Wang, Chengshan Yuan*, Hao-Li Zhang, and Xiangfeng Shao*. Org. Chem. Front. 2019, 6, 263–272.
14. Driving π-plane to π-bowl through the lateral coordination at room temperature. Ruili Geng, Xueqing Hou, Yantao Sun, Chaoxian Yan, Yuewei Wu, Haoli Zhang, and Xiangfeng Shao*. Mater. Chem. Front. 2018, 2, 1456–1461.
15. Opening Two Benzene Rings on Trichalcogenasumanenes toward High Performance Organic Optical-Limiting Materials. Xueqing Hou, Jibin Sun*, Zhe Liu, Chaoxian Yan, Wenru Song, Haoli Zhang, Shuyun Zhou, and Xiangfeng Shao*. Chem. Commun. 2018, 54, 10981–10984.
16. Remarkable Nonlinear Optical Response of Pyrazine-fused Trichalcogenasumanenes and Their Application for Optical Power Limiting. Jibin Sun*, Yantao Sun, Chaoxian Yan, Dongxu Lin, Zheng Xie, Shuyun Zhou, Chengshan Yuan*, Haoli Zhang, and Xiangfeng Shao*. J. Mater. Chem. C 2018, 6, 13114-13119.
17. Trichalcogenasumanene ortho-Quinones: Synthesis, Properties, and Transformation into Various Heteropolycycles. Yantao Sun, Xuexiang Li, Chunlin Sun, Hongguang Shen, Xueqing Hou, Dongxu Lin, Haoli Zhang, Chongan Di, Daoben Zhu, and Xiangfeng Shao*. Angew. Chem. Int. Ed. 2017, 56, 13470–13474.
18. 4, 5, 9, 10-Pyrene Diimides: A Family of Aromatic Diimides Exhibiting High Electron Mobility and Two-Photon Excited Emission. Zehua Wu, Zhuoting Huang, Ruixue Guo, Chunlin Sun, Lichuan Chen, Bing Song, Zifa Shi, Xiangfeng Shao, Hanying Li*, and Haoli Zhang*. Angew. Chem.Int. Ed. 2017, 56, 13031-13035.
19. Tris(S,S-dioxides)-trithiasumanene: Strong Fluorescence and Cocrystal with 1, 2, 6, 7, 10, 11-Hexabutoxytriphenylene (HBT). Xueqing Hou, Yongtao Zhu, Yunke Qin, Lichuan Chen, Xuexiang Li, Haoli Zhang, Wei Xu, Daoben Zhu, and Xiangfeng Shao*. Chem. Commun. 2017, 53, 1546-1549.
20. A Bowl-shaped Sumanene Derivative with Dense Convex-Concave Columnar Packing for High-Performance Organic Field-Effect Transistors. Beibei Fu, Xueqing Hou, Cong Wang, Yu Wang, Xiaotao Zhang, Rongjin Li*, Xiangfeng Shao*, and Wenping Hu. Chem. Commun. 2017, 53, 11407-11409.
21. Dissecting Trichalcogenasumanenes: π-Bowl to Planar, Invertible Curvature, and Chiral Polycycles. Xueqing Hou, Xuexiang Li, Chunlin Sun, Lichuan Chen, Yantao Sun, Zhe Liu, Haoli Zhang, and Xiangfeng Shao*. Chem.-Eur. J. 2017, 23, 14375-14383.
22. Tritellurasumanene: Ultrasound Assisted One-Pot Synthesis and Extended Valence Adduct with Bromine. Shitao Wang, Xuexiang Li, Xueqing Hou, Yantao Sun, and Xiangfeng Shao*. Chem. Commun. 2016, 52, 14486-14489.
23. Aryl-fused Tetrathianaphthalene (TTN): Synthesis, Structures, Properties, and Cocrystals with Fullerenes. Yantao Sun, Zili Cui, Lichuan Chen, Xiaofeng Lu, Yuewei Wu, Haoli Zhang, and Xiangfeng Shao*. RSC Adv. 2016, 6, 79978-79986.
24. Bowl-Shaped Conjugated Polycycles. Xueqing Hou, Yantao Sun, Lei Liu, Shitao Wang, Ruili Geng, Xiangfeng Shao*. Chinese Chem. Lett. 2016, 27, 1166-1174. (Invited review)
25. Ring Reconstruction on a Trichalcogenasumanene Buckybowl: A Facile Approach to Create Donor-Acceptor Type [5-6-7]-Fused Planar Polyheterocycles. Xuexiang Li, Yongtao Zhu, Jiafeng Shao, Lichuan Chen, Sijie Zhao, Baolin Wang, Shangxi Zhang, Yongliang Shao, Haoli Zhang, and Xiangfeng Shao*. Angew. Chem. Int. Ed. 2015, 54, 267-271.
26. Honeycomb Supramolecular Frameworks of Organic-Inorganic Hybrid Cluster Composed of Cation Radical and Keggin-Type Polyoxometalate. Shangxi Zhang, Jibin Sun, Xiaofeng Lu, Yali Zhao, and Xiangfeng Shao*. Crystengcomm 2015, 17, 4110-4116.
27. Copper Ion Salts of Arylthiotetrathiafulvalenes: Synthesis, Structure Diversity and Magnetic Properties. Longfei Ma, Jibin Sun, Xiaofeng Lu, Shangxi Zhang, Hui Qi, Lei Liu, Yongliang Shao, and Xiangfeng Shao*. Beilstein J. Org. Chem. 2015, 11, 850-859.
28. Donor-Acceptor Type Co-crystals of Thioarylated Tetrathiafulvalenes and Fullerenes. Xiaofeng Lu, Jibin Sun, Shangxi Zhang, Longfei Ma, Lei Liu, Hui Qi, Yongliang Shao, and Xiangfeng Shao*. Beilstein J. Org. Chem. 2015, 11, 1043–1051.
29. Non-Pyrolytic, Large-Scale Synthesis of Trichalcogenasumanene: A Two-Step Approach. Xuexiang Li, Yongtao Zhu, Jiafeng Shao, Baolin Wang, Shangxi Zhang, Yongliang Shao, Xiaojie Jin, Xiaojun Yao, Ran Fang, and Xiangfeng Shao*, Angew. Chem. Int. Ed. 2014, 53, 535–538.
30. Decorating Tetrathiafulvalene (TTF) with Fluorinated-Phenyls through Sulfur Bridges: Facile Synthesis, Properties, and Aggregation via Fluorine Interaction. Xiaofeng Lu, Jibin Sun, Yu Liu, Jiafeng Shao, Longfei Ma, Shangxi Zhang, Jinlian Zhao, Yongliang Shao, Haoli Zhang, Zhaohui Wang, and Xiangfeng Shao*. Chem.-Eur. J. 2014, 20, 9650-9656.
31. Inclusion Complexes of Fullerenes with Flexible Tetrathiafulvalene Derivatives Bearing Four Aryls through the Sulfur Bridges. Jibin Sun, Xiaofeng Lu, Manabu Ishikawa, Yoshiaki Nakano, Shangxi Zhang, Jinlian Zhao, Yongliang Shao, Zhaohui Wang, Hideki Yamochi, and Xiangfeng Shao*. J. Mater. Chem. C, 2014, 2, 8071–8076.
32. Synthesis of Di- and Tri-Xanthones Displaying High Stability and Visual Fluorescence Response to Strong Acid. Baoling Wang, Jiafeng Shao, Taoshan Xu, Lichuan Chen, Jinlian Zhao, Yongliang Shao, Haoli Zhang, and Xiangfeng Shao*. Chem.-Asian J. 2014, 9, 3307-3312.
33. Synthesis of Heterasumanene. Xuexiang Li, and Xiangfeng Shao*. Synlett 2014, 25, 1795-1798. (Invited review)
34. Mapping Molecular Motions Leading to Charge Delocalization with Ultrabright Electrons. Meng Gao, Cheng Lu, Hubert Jean-Ruel, Lai Chung Liu, Alexander Marx, Ken Onda, Shin-ya Koshihara, Yoshiaki Nakano, Xiangfeng Shao, Takaaki Hiramatsu, Gunzi Saito, Hideki Yamochi, Ryan R. Cooney, Gustavo Moriena, Germán Sciaini, and R. J. Dwayne Miller*. Nature 2013, 496, 343–346.
35. Molecular and Crystal Ctructure diversity, and Physical Properties of Tetrathiafulvalene Derivatives Substituted with Various Aryls through Sulfur Bridges. Jibin Sun, Xiaofeng Lu, Jiafeng Shao, Xuexiang Li, Shangxi Zhang, Baolin Wang, Jinlian Zhao, Yongliang Shao, Ran Fang, Zhaohui Wang, Wei Yu, and Xiangfeng Shao*. Chem.- Eur. J. 2013, 19, 12517-12525.
36. Straightforward Access to Aryl-Substituted/Fused 1, 3-Dithiole-2-chalcogenones by Cu-Catalyzed C-S Coupling between Aryl Iodides and Zinc-thiolate Complex (TBA)2[Zn(DMIT)2]. Jibin Sun, Xiaofeng Lu, Jiafeng Shao, Zili Cui, Yu Shao, Guiyang Jiang, Wei Yu, and Xiangfeng Shao*. RSC Adv. 2013, 3, 10193-10196.
37. Copper-catalyzed Decarboxylative Alkenylation of sp3-C-H Bonds with Cinnamic Acids via a Radical Process. Zili Cui, Xiaojie Shang, Xiangfeng Shao, and Zhongquan Liu. Chem. Sci. 2012, 3, 2853–2858.
38. Structures and Physical Properties of Magnetic Organic Conductors Based on Bent Bonor Molecule EDT-EDSe-TTFVS. Jibin Sun, Jiafeng Shao, Guiyang Jiang, Xiaofeng Lu, Shangxi Zhang, Xuexiang Li, Baolin Wang, Toyonari Sugimoto, and Xiangfeng Shao*. Synthetic Met. 2012, 162, 1809-1814.
39. Quasi-one-dimensional (Q1D) Organic Mott Insulators Based on Bent Donor Molecule EDO-EDSe-TTFVS. Shangxi Zhang, Jiafeng Shao, Jibin Sun, Guiyang Jiang, Yali Zhao, Zili Cui, Jinlian Zhao, and Xiangfeng Shao*. Synthetic Met. 2012, 162, 2342–2348.
40. Tuning of Multi-Instabilities in Organic Alloy, [(EDO-TTF)1-x(MeEDO-TTF)x]2PF6. Tsuyoshi Murata*, Xiangfeng Shao, Yoshiaki Nakano, Hideki Yamochi*, Mikio Uruichi, Kyuya Yakushi, Gunzi Saito, and Koichiro Tanaka. Chem. Mater. 2010, 22, 3121-3132.
41. Prediction about the Electronic Structure via Molecular Stacking Mode of Radical Cation Salts Based on Asymmetric Donor Molecule MeEDO-TTF. Xiangfeng Shao*, Yukihiro Yoshida, Yoshiaki Nakano, Hideki Yamochi*, Masafumi Sakata, Mitsuhiko Maesato, Akihiro Otsuka, Gunzi Saito, and Shinya Koshihara. Chem. Mater. 2009, 21, 1085-1095.
42. Template-free Growth of Micro/Nanocrystals of Magnetic Molecular Conductors by Electrocrystallization on Platinum Electrode. Xiangfeng Shao*, Yuhta Yamaji, Toyonari Sugimoto*, Hisashi Tanaka, Dominique de Caro, and Lydie Valade. Chem. Mater. 2009, 21, 5569-5571.
43. Interconvertable Bistability in Magnetic Molecular Conductors Based on Bent Donor Molecules, EDO-EDSe-TTFVS(O). Xiangfeng Shao* , Yuhta Yamaji, Hideki Fujiwara, and Toyonari Sugimoto*. J. Mater. Chem. 2009, 19, 5837-5844.
44. Antiferromagnetic Ordering of Fe(III) d-spins of FeBr4-Ions via Strong π-d Interactions in Charge-Transfer Complexes [EDT(O)-CP-TTFVS] FeBr4. Xiangfeng Shao*, Yuhta Yamaji, and Toyonari Sugimoto*. J. Mater. Chem. 2009, 19, 3688-3695.
45. Photo-induced Change in the Charge Order Pattern in the Quarter-filled Organic Conductor (EDO-TTF)2PF6 with Strong Electron-Phonon Interaction. Ken Onda*, Sho Ogihara, Kenji Yonemitsu, Nobuya Maeshima, Tadahiko Ishikawa, Yoichi Okimoto, Xiangfeng Shao, Yoshiaki Nakano, Hideki Yamochi, Gunzi Saito, and Shin-ya Koshihara*. Phys. Rev. Lett. 2008, 101, 067403/1–4.
46. Room Temperature First-order Phase Transition in a Molecular Conductor (MeEDO-TTF)2PF6. Xiangfeng Shao*, Yoshiaki Nakano, Masafumi Sakata, Hideki Yamochi*, Yukihiro Yoshida, Mitsuhiko Maesato, Mikio Uruichi, Kyuya Yakushi, Tsuyoshi Murata, Akihiro Otsuka, Gunzi Saito, Shin-ya Koshihara, and Koichiro Tanaka. Chem. Mater. 2008, 20, 7551-7562.
47. Formation of Two-dimensional Metals by Weak Intermolecular Interactions Based on the Asymmetric EDO-TTF Derivatives. Xiangfeng Shao*, Yoshiaki Nakano, Hideki Yamochi*, Alexander D. Dubrovskiy, Akihiro Otsuka, Tsuyoshi Murata, Yukihiro Yoshida, Gunzi Saito, Shin-ya Koshihara. J. Mater. Chem. 2008, 18, 2131-2140.
