舒兴中
2015-至今 兰州大学化学化工学院、功能有机分子化学国家重点实验室,教授
2012-2015 加州大学伯克利分校/劳伦斯伯克利国家实验室 (导师: F. Dean Toste教授),博士后
2010-2012 威斯康辛大学麦迪逊分校 (导师: Weiping Tang教授),博士后
2005-2010 兰州大学 (导师: 梁永民 教授),理学博士
2001-2005 绍兴文理学院,学士
•荣誉奖励
2023 “长江学者奖励计划”特聘教授
2022 国华青年英才奖
2020 兰州大学五四青年奖章
2020 Thieme Chemistry Journals Award
2009 中国青少年科技创新奖
2008 宝钢教育奖学金
•研究兴趣
研究兴趣为有机合成方法学。目前主要的研究方向包括:(1)非活性C-O键还原偶联化学;(2)氯硅(锗)烷还原偶联化学;(3)不对称还原偶联化学。
•代表成果
1. Enantioconvergent and Regioselective Reductive Coupling of Propargylic Esters with Chlorogermanes by Nickel Catalysis. Guan-Yu Han, Pei-Feng Su, Qiu-Quan Pan, Xue-Yuan Liu, and Xing-Zhong Shu*, Nat. Catal. 2024, 7, 12.
2. Nickel-Catalyzed Reductive [4 + 1] Sila-Cycloaddition of 1,3-Dienes with Dichlorosilanes. Liangliang Qi, Qiu-Quan Pan, Xiao-Xue Wei, Xiaobo Pang, Zitong Liu, and Xing-Zhong Shu*, J. Am. Chem. Soc. 2023, 145, 13008.
3. Enantioselective Reductive N‑Cyclization Alkylation Reaction of Alkene-Tethered Oxime Esters and Alkyl Iodides by Nickel Catalysis. Xuegong Jia, Qiwei Yao, and Xingzhong Shu*, J. Am. Chem. Soc. 2022, 144, 13461.
4. Nickel-Catalyzed Reductive C(sp2)-Si Coupling of Chlorohydrosilanes via Si-Cl Cleavage. Zhenzhen Zhao, Xiaobo Pang, Xiaoxue Wei, Xueyuan Liu and Xingzhong Shu*, Angew. Chem. Int. Ed. 2022, 61, e202200215.
5. Nickel-Catalyzed Cross-Electrophile 1,2-Silyl-Arylation of 1,3-Dienes with Chlorosilanes and Aryl Bromides. Qiuquan Pan, Liangliang Qi, Xiaobo Pang, and Xing-Zhong Shu*, Angew. Chem. Int. Ed. 2023, 62, e202215703.
6. Reductive Cross-Coupling of Unreactive Electrophiles. Xiaobo Pang, Pei-Feng Su, and Xing-Zhong Shu*, Acc. Chem. Res. 2022, 55, 2491.
7. Ti-Catalyzed Reductive Dehydroxylative Vinylation of Tertiary Alcohols. Hao Xie, Sheng Wang, Yuquan Wang, Peng Guo and Xing-Zhong Shu*, ACS Catal. 2022, 12, 1018.
8. Reductive Alkylation of Alkenyl Acetates with Alkyl Bromides by Nickel Catalysis. Rong-De He, Yunfei Bai, Guan-Yu Han, Zhen-Zhen Zhao, Xiaobo Pang, Xiaobo Pan, Xue-Yuan Liu, Xing-Zhong Shu*. Angew. Chem. Int. Ed. 2021, 61, e202114556.
9. Nickel-Catalyzed Reductive C−Ge Coupling of Aryl/Alkenyl Electrophiles with Chlorogermanes. Pei-Feng Su‡, Ke Wang‡, Xuejing Peng, Xiaobo Pang, Peng Guo, and Xing-Zhong Shu*. Angew. Chem. Int. Ed. 2021, 60, 26571-26576.
10. Cobalt-Catalyzed Enantiospecific Dynamic Kinetic Cross-Electrophile Vinylation of Allylic Alcohols with Vinyl Triflates. Wei-Yuan Ma, Guan-Yu Han, Shaolin Kang, Xiaobo Pang, Xue-Yuan Liu, Xing-Zhong Shu. J. Am. Chem. Soc. 2021, 143, 15930-15935.
11. Enantioselective Reductive Divinylation of Unactivated Alkenes by Nickel-Catalyzed Cyclization Coupling Reaction. Jin-Bao Qiao‡, Ya-Qian Zhang‡, Qi-Wei Yao, Zhen-Zhen Zhao, Xuejing Peng, and Xing-Zhong Shu. J. Am. Chem. Soc. 2021, 143, 12961-12967.
12. Regiocontrolled Reductive Vinylation of Aliphatic 1,3-Dienes with Vinyl Triflates by Nickel Catalysis. Xiaobo Pang, Zhen-Zhen Zhao, Xiao-Xue Wei, Liangliang Qi, Guang-Li Xu, Jicheng Duan, Xue-Yuan Liu, and Xing-Zhong Shu. J. Am. Chem. Soc. 2021, 143, 4536-4542.
13. Dynamic Kinetic Cross-Electrophile Arylation of Benzyl Alcohols by Nickel Catalysis. Peng Guo, Ke Wang, Wen-Jie Jin, Hao Xie, Liangliang Qi, Xue-Yuan Liu, and Xing-Zhong Shu. J. Am. Chem. Soc. 2021, 143, 513-523.
14. Nickel-Catalyzed Cross-Electrophile C(sp3)-Si Coupling of Unactivated Alkyl Bromides with Vinyl Chlorosilanes. Jicheng Duan, Yuquan Wang, Liangliang Qi, Peng Guo, Xiaobo Pang, Xing-Zhong Shu*, Org. Lett. 2021, 23, 7855-7859.
15. Nickel-Catalyzed Cross-Electrophile C(sp3)–Si Coupling of Unactivated Alkyl Bromides with Vinyl Chlorosilanes. CCS Chem.2021, 3, 1147-1154.
16. Titanium: a Unique Metal for Radical Dehydroxylative Functionalization of Alcohols. Xiaobo Pang, Xing-Zhong Shu*, Synlett 2021, 32, 1269-1274.
17. Synthesis of Dibenzyls Synthesis by Nickel-Catalyzed Homocoupling of Benzyl Alcohols. Feng-Feng Pan, Peng Guo, Xiaochuang huang, Xing-Zhong Shu*, Synthesis-Stuttgart 2021, 53, 3094-3100.
18. Cross-Electrophile Csp2-Si Coupling of Vinyl Chlorosilanes. Jicheng Duan, Ke Wang, Guangli Xu, Shaolin Kang, Liangliang Qi, Xueyuan Liu, and Xingzhong Shu*. Angew. Chem. Int. Ed. 2020, 59, 23083-23088.
19. Radical Dehydroxylative Alkylation of Tertiary Alcohols by Ti Catalysis. Hao Xie, Jiandong Guo, Yuquan Wang, Ke Wang, Peng Guo, Peifeng Su, Xiaotai Wang*, and Xingzhong Shu*. J. Am. Chem. Soc. 2020, 142, 16787-16794.
20. Allylboronates from Vinyl Triflates and α-Chloroboronates by Reductive Nickel Catalysis. Jinbao Qiao, Zhenzhen Zhao, Yaqian Zhang, Kai Yin, Zhixiong Tian, and Xingzhong Shu*. Org. Lett. 2020, 22, 5085-5089.
21. Reductive Coupling between C-N and C-O Electrophiles. Rongde He, Chunling Li, Qiuquan Pan, Peng Guo, Xueyuan Liu, and Xingzhong Shu*. J. Am. Chem. Soc. 2019, 141, 12481-12486.
22. Highly Enantioselective Cross-Electrophile Aryl-Alkenylation of Unactivated Alkenes. Zhixiong Tian, Jinbao Qiao, Guangli Xu, Xiaobo Pang, Liangliang Qi, Weiyuan Ma, Zhenzhen Zhao, Jicheng Duan, Yunfei Du, Peifeng Su, Xueyuan Liu, and Xingzhong Shu*. J. Am. Chem. Soc. 2019, 141, 7637-7643.
23. Ni-catalyzed cross-electrophile coupling between vinyl/aryl and alkyl sulfonates: synthesis of cycloalkenes and modification of peptides. Jicheng Duan, Yunfei Du, Xiaobo Pang, and Xingzhong Shu*. Chem. Sci. 2019, 10, 8706-8712.
24. Enones from Acid Fluorides and Vinyl Triflates by Reductive Nickel Catalysis. Fengfeng Pan, Peng Guo, Chunling Li, Peifeng Su, and Xingzhong Shu*. Org. Lett. 2019, 21, 3701-3705.
25. Dual nickel and Lewis acid catalysis for cross-electrophile coupling: the allylation of aryl halides with allylic alcohols. Xuegong Jia, Peng Guo, Jicheng Duan, and Xingzhong Shu*. Chem. Sci. 2018, 9, 640-645.
26. Reductive coupling of benzyl oxalates with highly functionalized alkyl bromides by nickel catalysis. Xiaobiao Yan, Chunling Li, Wenjie Jin, Peng Guo, and Xingzhong Shu*. Chem. Sci. 2018, 9, 4529-4534.
27. Silica-Supported Cationic Gold(I) Complexes as Heterogeneous Catalysts for Regio- and Enantioselective Lactonization Reactions. Xingzhong Shu, Son C. Nguyen, Ying He, Fadekemi Oba, Qiao Zhang, Christian Canlas, Gabor A. Somorjai*, A. Paul Alivisatos*, and F. Dean Toste*. J. Am. Chem. Soc. 2015, 137, 7083.
28. Dual Visible Light Photoredox and Gold-catalyzed Arylative Ring Expansion. Xingzhong Shu, Miao Zhang, Ying He, Heinz, Frei*, and F. Dean Toste*. J. Am. Chem. Soc. 2014, 136, 5844.
29. Transfer of Chirality in Rhodium-Catalyzed Intramolecular (5+2) Cycloaddition of 3-Acyloxy-1, 4-enyne (ACE) and Alkyne: Enantioselective Synthesis of Bicyclo[5.3.0]decatrienes. Xingzhong Shu, Casi M. Schienebeck, Wangze Song, Ilia A. Guzei, and Weiping Tang*. Angew. Chem. Int. Ed. 2013, 52, 13601.
30. Rhodium-Catalyzed Intra- and Intermolecular 5+2 Cycloaddition of 3-Acyloxy-1, 4-enyne and Alkyne with Concomitant 1, 2-Acyloxy Migration, Xingzhong Shu, Xiaoxun Li, Dongxu Shu, Suyu Huang, Casi Mae Schienebeck, Xin Zhou, Patrick J. Robichaux, and Weiping Tang. J. Am. Chem. Soc. 2012, 134, 5211.