许鹏飞
2003-至今 兰州大学化学化工学院、功能有机分子化学国家重点实验室,教授
2019-2022 兰州大学校长助理
2018-2022 科学技术发展研究院执行院长
2015-2018 兰州大学萃英学院执行院长
2009-2015 兰州大学教务处处长
2003-2004 日本名古屋大学物质材料科学国际研究中心(K. Tatsumi合作教授), 访问教授
1999-2001 台湾中兴大学,博士后(陈大荣教授)
1996-1998 兰州大学,理学博士(张自义教授)
1992-1994 兰州大学,理学硕士(吴绍祖教授)
1983-1987 兰州大学,化学系有机化学专业,理学学士(李瑜教授)
• 荣誉奖励
2023 国家级教学成果奖二等奖(第一完成人)
2023 隆基教学名师奖
2023 宝钢优秀教师奖
2021 甘肃省高等教育教学成果特等奖(第一完成人)
2021 入选第二批甘肃省拔尖领军人才
2019 甘肃省自然科学一等奖(第一完成人);
2016 兰州大学国华杰出学者奖;
2014 全国宝钢优秀教师奖;
2014 甘肃省科技进步一等奖(第一完成人);
2013 兰州大学“师德标兵”,甘肃省“陇原师德先进个人”称号;
2012 金川集团科技进步一等奖,国务院政府特殊津贴;
2010 甘肃省自然科学一等奖(第一完成人);
2009 入选甘肃省领军人才,Thieme Chemistry Journal Award;
2005 入选教育部“新世纪优秀人才支持计划”、甘肃省“555”创新人才;
2002 第九届甘肃省青年教师成才奖,甘肃省科技进步三等奖两项
• 研究兴趣
1) α-氨基酸的不对称合成及方法研究;
2) 有机小分子催化的不对称串联反应的研究;
3) 天然产物结构导向的有机小分子催化反应的研究;
4) 可见光催化的有机反应研究;
5) 新型可见光催化剂的设计与应用;
6) 新型浮选剂的研发。
• 代表成果
1. A Novel Approach for Synthesizing α-amino Acids via Formate Mediated Hydrogen Transfer using a Carbon Source. Tian-Tian Zhao‡, Xu-Gang Zhang‡, Wen-Bo He and Peng-Fei Xu *, Green Commun., 2023, 25, 8539.
2. Organic Photoredox Catalyzed Dealkylation/Acylation of Tertiary Amines to Access Amides. Chen Liu‡, Han-Nan Chen‡, Teng-Fei Xiao, Xiu-Qin Hu*, Peng-Fei Xu, and Guo-Qiang Xu*, Chem. Commun., 2023, 59, 2003.
3. Light-Promoted Nickel-Catalyzed C-O/C-N Coupling of Aryl Halides with Carboxylic Acids and Sulfonamides. Tian-Tian Zhao, Hao-Ni Qin, and Peng-Fei Xu*, Org. Lett., 2023, 25, 636.
4. Pcet-Mediated Ring-Opening Alkenylation of Cycloalkanols via Dual Photoredox and Cobalt Catalysis. Zi-Gang Ren, Wan-Lei Yu, Hai-Xue Zheng, and Peng-Fei Xu*, Org. Lett., 2023, 25, 93.
5.Solvent Directed Chemically Divergent Synthesis of β-lactams and α-amino Acid Derivatives With Chiral Isothiourea. Dong-Sheng Ji, Hui Liang, Kai-Xuan Yang, Zhi-Tao Feng, Yong-Chun Luo*, Guo-Qiang Xu, Yucheng Gu, and Peng-Fei Xu*, Chem. Sci. 2022, 13, 1801.
6.Cobalt-catalyzed Chemoselective Dehydrogenation Through Radical Translocation Under Visible Light. Wan-Lei Yu, Zi-Gang Ren, Ke-Xing Ma, Hui-Qing Yang, Jun-Jie Yang, Haixue Zheng*, Wangsuo Wu, and Peng-Fei Xu*, Chem. Sci. 2022, 13, 7947.
7. Organophotoredox Catalytic four-component Radical-polar Crossover Cascade Reactions for the Stereoselective Synthesis of β-amido Sulfones. Sheng-Qiang Guo, Hui-Qing Yang, Yu-Zhen Jiang, Ai-Lian Wang, Guo-Qiang Xu, Yong-Chun Luo, Zhao-Xu Chen, Haixue Zheng*, and Peng-Fei Xu*, Green Chem. 2022, 24, 3120.
8. Photoredox/Nickel Dual Catalyzed Stereospecific Synthesis of Distal Alkenyl Ketones. Tian-Tian Zhao, Wan-Lei Yu, Zhi-Tao Feng, Hao-Ni Qin, Haixue Zheng*, and Peng-Fei Xu*, Chem. Commun. 2022, 58, 1171.
9. Organocatalytic Inverse-Electron-Demand Diels-Alder Reaction Between 5-alkenyl Thiazolones and β,γ-Unsaturated Carbonyl Compounds. Kai-Xuan Yang, Dong-Sheng Ji, Haixue Zheng, Yucheng Gu*, and Peng-Fei Xu*, Chem. Commun. 2022, 58, 4227.
10. Divergent Ritter-type Amination via Photoredoxcatalytic Four-Component Radical-Polar Crossover Reactions. Sheng-Qiang Guo, Hui-Qing Yang, Ai-Lian Wang, Yu-Zhen Jiang, Guo-Qiang Xu, Yong-Chun Luo*, Zhao-Xu Chen, Peng-Fei Xu*, Green Chem. 2021, 23, 9571-9576.
11. Visible-Light Induced Generation of Bifunctional Nitrogen-Centered Radicals: A Concise Synthetic Strategy to Construct Bicyclo-[3.2.1]octane and Azepane Cores. Wanlei Yu, Haowen Jiang, Lei Yan, Zhitao Feng, Yongchun Luo, Pengfei Xu*. Sci. China Chem. 2021, 64, 274-280.
12. Photoredox Catalyzed Hydrocarboxymethylation of Alkenes. Jie Fang, Qiang Hu, Wanli Dong, Guoqiang Xu, Xiuqin Hu, Yongchun Luo, and Pengfei Xu*. CCS Chem. 2021, 43, 95-104.
13. Highly Enantioselective Construction of Strained Spiro[2,3]hexanes via Michael-Ring Expansion-Cyclization Cascade Strategy. Chuangang Zhao, Zhitao Feng, Guoqiang Xu*, Ang Gao, Jingwei Chen, Zhuyin Wang, and Pengfei Xu*. Angew. Chem. Int. Ed. 2020, 59, 3058-3062.
14. A lutidine-promoted photoredox catalytic atom-transfer radical cyclization reaction for the synthesis of 4-bromo-3,3-dialkyl-octahydroindol-2-ones. Quansheng Zhao, Guoqiang Xu, Jitao Xu, Zhuyin Wang, and Pengfei Xu*. Chem. Commun. 2020, 56, 2206-2209.
15. Enantioselective Synthesis of Spirorhodanine-Pyran Derivatives via Organocatalytic [3+3] Annulation Reactions between Pyrazolones and Rhodanine-Derived Ketoesters. Dongsheng Ji, Yongchun Luo, Xiuqin Hu, and Pengfei Xu*. Org. Lett. 2020, 22, 1028−1033.
16. Asymmetric Organocatalytic [4+1] Annulations Involving a Polarity Reversal Process: A Tandem Catalytic Approach to Highly Functionalized piropyrazolone Derivatives. Changyin Tan, Hong Lu, Jialu Zhang, Jinyu Liu, and Pengfei Xu*. J. Org. Chem. 2020, 85, 594−602.
17. Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen-Atom Transfer, and Cobalt Catalysis. Wanlei Yu, Yongchun Luo, Lei Yan, Dan Liu, Zhuyin Wang, and Pengfei Xu*.Angew. Chem. Int. Ed. 2019, 58, 10941.
18. Ni-Catalyzed 1,2-Acyl Migration Reactions Triggered by C–C Bond Activation of Ketones. Cheng Jiang, Hong Lu, Wenhua Xu, Jianing Wu, Tianyang Yu, Pengfei Xu, and Hao Wei*. ACS Catal. 2019, 10, 1947-1975.
19. Photocatalyzed Metal-Free Alkylheteroarylation of Unactivated Olefins via Direct Acidic C(sp3)−H Bond Activation. Jie Fang, Wanli Dong, Guoqiang Xu, and Pengfei Xu*. Org. Lett. 2019, 21, 4480−4485.
20. Metal-Free Visible-Light-Induced Construction of Difluoro- Containing Dibenzazepines. Dan Liu, Mengjie Jiao, Xingzhi Wang, and Pengfei Xu*.Org. Lett. 2019, 21, 4745.
21. An Atropo-enantioselective Synthesis of Benzo-Linked Axially Chiral Indoles via Hydrogen-Bond Catalysis. Jinyu Liu, Xiechao Yang, Zhen Liu, Yongchun Luo, Hong Lu, Yucheng Gu, Ran Fang, and Pengfei Xu*.Org. Lett. 2019, 21, 5219.
22. Aroylchlorination of 1,6-Dienes via a Photoredox Catalytic Atom-Transfer Radical Cyclization Process. Quansheng Zhao, Guoqiang Xu, Hui Liang, Zhuyin Wang, and Pengfei Xu*. Org. Lett. 2019, 21, 8615.
23. Synthesis of indolo[2,1-a]isoquinoline derivatives via visible-light-induced radical cascade cyclization reactions. Yunlong Wei, Jianqiang Chen, Bo Sun, and Pengfei Xu*. Chem. Commun. 2019, 55, 5922.
24. Directed Decarbonylation of Unstrained Aryl Ketones via Nickel-Catalyzed C-C Bond Cleavage. Tiantian Zhao, Wen-Hua Xu, Zhaojing Zheng, Pengfei Xu*, and Hao Wei*. J. Am. Chem. Soc. 2018, 140, 586.
25. Dual Csp3-H Bond Functionalization of N-Heterocycles via Visible-Light Photocatalyzed Dehydrogenation /[2+2] Cycloaddition Sequential Reaction. Guoqiang Xu, Jitao Xu, Zhitao Feng, Hui Liang, Zhuyin Wang, Yong Qin, and Pengfei Xu*. Angew. Chem. Int. Ed. 2018, 57, 5110.
26. Organocatalytic, Enantioselective Friedel−Crafts Reaction of Indoles in the Carbocyclic Ring and Electron-Rich Phenols. Jinyu Liu, Xiechao Yang, Hong Lu, Yucheng Gu, and Pengfei Xu*. Org. Lett. 2018, 20, 2190.
27. Photoredox-Induced Intramolecular 1,5‑H Transfer Reaction of Aryl Iodides for the Synthesis of Spirocyclic γ‑Lactams. Jianqiang Chen, Rui Chang, Junbing Lin, Yongchun Luo, and Pengfei Xu*. Org. Lett. 2018, 20, 2395.
28. Regiospecific Three-Component Aminofluorination of Olefins via Photoredox Catalysis. Jianan Mo, Wanlei Yu, Jianqiang Chen, Xiuqin Hu*, and Pengfei Xu*. Org. Lett. 2018, 20, 4471.
29. Design, Synthesis, and Application of Highly Reducing Organic Visible-Light Photocatalysts. Liu Dan, Jiao Mengjie, Feng Zhitao, Wang Xingzhi, Xu Guoqiang, and Xu Pengfei*. Org. Lett. 2018, 20, 5700.
30. Dearomative Dienolate-Mediated Catalysis: A Remote Activation Strategy for Asymmetric Functionalization of Benzylic C−H Bonds of Heteroaryl Aldehydes. Yang Wang, Junbing Lin, Jikang Xie, Hong Lu, Xiuqin Hu, and Pengfei Xu*.Org. Lett. 2018, 20, 5835.
31. Alkene functionalization for the stereospecific synthesis of substituted aziridines by visible-light photoredox catalysis. Wanlei Yu, Jianqiang Chen, Yunlong Wei, Zhuyin Wang, and Pengfei Xu*. Chem. Commun. 2018, 54, 1948-1951.
32. A new approach to access difluoroalkylated diarylmethanes via visible-light photocatalytic cross-coupling reactions. Zhao Yinna, Luo Yongchun, Wang Zhuyin, and Xu Pengfei*. Chem. Commun. 2018, 54, 3993.
33. Synthesis of five-membered cyclic nitrones based on the Lewis acid-catalysed [3+2]-annulation reaction of donor–acceptor cyclopropanes with 1,4,2-dioxazoles. Xu Pengfei*, Zhang Huanhuan, Luo Yongchun, Wang Zhehao. Chem. Commun. 2018, 54, 10128.
34. N‑Heterocyclic Carbene-Catalyzed Atom-Economical and Enantioselective Construction of the C−S Bond: Asymmetric Synthesis of Functionalized Thiochromans. Hong Lu, Jialu Zhang, Jinyu Liu, Hongyu Li, and Pengfei Xu*. ACS Catal. 2017, 7, 7797.
35. 3,4,5-Trimethylphenol and Lewis Acid Dual-Catalyzed Cascade Ring-Opening/Cyclization: Direct Synthesis of Naphthalenes. Ma He, Hu Xiuqin, and Xu Pengfei*, Luo Yongchun. Org. Lett. 2017, 19, 6666.
36. Visible-Light-Induced Aza-Pinacol Rearrangement: Ring Expansion of Alkylidenecyclopropanes. Wendeng Liu, Guoqiang Xu, Xiuqin Hu, and Pengfei Xu*. Org. Lett. 2017, 19, 6291.
37. Highly Enantioselective Construction of Hajos-Wiechert Ketone Skeletons via an Organocatalytic Vinylogous Michael/Stetter Relay Sequence. Zhilong Jia, Yao Wang, Chuangang Zhao, Xiaohai Zhang, and Pengfei Xu*.Org. Lett. 2017, 19, 2130.
38. Quaternary Carbon Center Forming Formal [3+3] Cycloaddition Reaction via Bifunctional Catalysis: Asymmetric Synthesis of Spirocyclohexene Pyrazolones. Jinyu Liu, Jing Zhao, Jialu Zhang, and Pengfei Xu*. Org. Lett. 2017, 19, 1846.
39. Synthesis of Fused Pyran Derivatives via Visible-Light-Induced Cascade Cyclization of 1,7-Enynes with Acyl Chlorides. Chenguang Li , Guoqiang Xu, and Pengfei Xu*, Org. Lett. 2017, 19, 512.
40. Rh(II) Catalyzed High Order Cycloadditions of 8-Azaheptafulvenes with N-Sulfonyl 1,2,3-Triazloes or α-Oxo Diazocompounds. Wei Chen, Yali Bai , Yongchun Luo , Pengfei Xu*. Org. Lett. 2017, 19, 364.
41. Lewis acid catalyzed diastereoselective [3+4]-annulation of donor-acceptor cyclopropanes with anthranils: synthesis of tetrahydro-1-benzazepine derivatives. Zhehao Wang, Huanhuan Zhang*, Daoming Wang, Pengfei Xu, and Yongchun Luo*. Chem. Commun. 2017, 53, 8521.
42. Kinetic resolution via supramolecular iminium catalysis: multiactivation enables the asymmetric synthesis of β-aryl substituted aldehydes and densely functionalized cyclohexanes. Zhilong Jia, Yao Wang*, Guoqiang Xua, and Pengfei Xu*. Chem. Commun. 2017, 53, 4938.
43. Asymmetric Catalytic Cascade Reactions for Constructing Diverse Scaffolds and Complex Molecules. Yao Wang, Hong Lu, and Pengfei Xu*. Acc. Chem. Res. 2015, 48, 1832.
44. Catalytic Cascade Reactions. Pengfei Xu, and Wei Wang. 2014,DOI:10.1002/9781118356654.
45. Rationally Designed Multifunctional Supramolecular Iminium Catalysis: Direct Vinylogous Michael Addition of Unmodified Linear Dienol Substrates. Yun Gu, Yao Wang, Tianyang Yu, Yongmin Liang, Pengfei Xu*. Angew. Chem. Int. Ed. 2014, 53, 14128.
46. Hydrogen-Bond-Mediated Supramolecular Iminium Ion Catalysis. Yao Wang, Tianyang Yu,Hongbo Zhang, Yongchun Luo, Pengfei Xu*. Angew. Chem. Int. Ed. 2012, 51, 12339.
47. Synthesis of a-Amino Acids Based on Chiral Tricycloiminolactone Derived from Natural (+)-Camphor. Yongchun Luo, Huanhuan Zhang, Yao Wang, and Pengfei Xu*. Acc. Chem. Res. 2010, 43, 1317.
48. Asymmetric Organocatalytic Relay Cascades: Catalyst-Controlled Stereoisomer Selection in the Synthesis of Functionalized Cyclohexanes. Yao Wang, Ronggang Han, Yonglong Zhao, Shu Yang, Pengfei Xu*, and Darren J. Dixon*. Angew. Chem. Int. Ed. 2009, 48, 9834.